Mar 04, 2017 aniline point represents the degree of aromaticity or simply the aromatic content of the given oil sample. Aniline is also known as aminobenzene or phenyl amine. Aniline market forecasts to 2018 marketsandmarkets. It is also used as a solvent, and has been used as an antiknock compound for gasolines.
Perform up to 3 aniline point tests simultaneously astm d 611, ip 2 t he ap611 from isl automatically determines aniline point of petroleum products and hydrocarbon solvents. Aniline point represents the degree of aromaticity or simply the aromatic content of the given oil sample. Aniline was first obtained in 1826 by the destructive distillation of indigo. Apr 19, 2012 aniline pointthe relative aromatic content of an oil isindicated by its aniline point. May 05, 2016 the aniline point is a physical characteristic of hydrocarbon compounds, such as oils, and refers to the minimum temperature at which the hydrocarbon and the same amount of the compound aniline c5h5nh2 are perfectly miscible. Images and videos of aniline add images and videos of aniline photos of aniline 0 add. Aniline pointthe relative aromatic content of an oil isindicated by its aniline point. For aniline point and mixed aniline point determinations according to method b.
Aniline, an organic base used to make dyes, drugs, explosives, plastics, and photographic and rubber chemicals. Aniline manufacture from nitrobenzene liquidphase aniline, also known as amino benzene or benzenamine, is an aromatic amine with the formula c 6 h 5 nh 2. Pdfcreator allows you to convert files to pdf, merge and rearrange pdf files, create digital signatures and more. Aniline is predominantly used as a chemical intermediate for the dye, agricultural, polymer, and rubber industries.
Aniline point definition is the lowest temperature at which aniline and a solvent as gasoline are completely miscible and which serves as an indication of the type of hydrocarbons present in the solvent, the content of aromatics being higher according as the temperature is lower. Add 20 ml of a mixture of acetic anhydride and glacial acetic acid equal volumes to 10 ml 10. Aniline also called as aminobenzene or phenylamine is an organic compound this report analyzes the global markets for aniline. Aniline can be toxic if ingested, inhaled, or by skin contact. Digital temperature display performs aniline point and mixed aniline point determinations automatically by means of a modified thin film technique astm d611.
Thin film aniline point apparatus conforms to astm d611 and related specifications for aniline point and mixed aniline point determinations according to method b. It is a colorless to pale yellow liquid rapidly becomes brown on exposure to air and light, with rotten odor, soluble in water. Based on the type of hydrocarbon solvent power of the crude oil is changed. Automatic aniline point apparatus, mixed aniline point. Like most volatile amines, it has the odor of rotten fish. At temperatures below this point, a mixture of the compound and an equal volume of aniline will not dissolve. The aniline point of an oil is defined as the minimum temperature at which equal volumes of aniline c 6 h 5 nh 2 and lubricant oil are miscible, i.
Apparatus performs handsfree aniline point and mixed aniline point determinations automatically by means of a modified thin film technique astm d611 method e. Its name is taken from the specific name of the indigoyielding plant indigofera anil indigofera. Aniline is slightly soluble in water and mixes readily with most organic solvents. This trend can be easily seen if aniline point values are compared. Aniline point definition of aniline point by merriamwebster. Aniline is an organic compound with the formula c 6 h 5 nh 2.
Its main use is in the manufacture of precursors to polyurethane and other industrial chemicals. Aniline being an aromatic compound freely mixes with aromatic so a low aniline point indicates low diesel index because of high percentage of aromatics. Word, excel, powerpoint, images and any other kind of document can be easily converted to pdf on. Free online pdf creator create pdf online with soda pdf. Standards are packaged in 20ml ampoules in an inert atmosphere. The sample is heated by a platinum immersion heater and the aniline point is detected photoelectrically. Aniline is used to make a wide variety of products such as polyurethane foam, agricultural chemicals, synthetic dyes, antioxidants, stabilizers for the rubber industry, herbicides. Aromatic hydrocarbons exhibit the lowest, and paraffins the highest values. Astm d611a, ip 2a aniline point and mixed aniline point of petroleum products and hydrocarbon solvents. Smallpdf pdf converter operates fully in the cloud. You can access the free pdf file converter anywhere, with an internet connection. This online pdf converter can convert all your files to pdf but also compress and merge pdf files. The term nitroaniline in chemistry refers to a derivative of aniline c 6 h 5 nh 2 containing a nitro group no 2 there are three simple nitroanilines of formula c 6 h 4 nh 2no 2 which differ only in the position of the nitro group. With the pdf unlock tool you can easily unlock your protected pdf files and remove the printing, copying and editing lock.
Aniline, an organic base used to make dyes, drugs, explosives, plastics, and photographic and rubber chemicals aniline was first obtained in 1826 by the destructive distillation of indigo. Oils having a high aromatic content have a low aniline point,since aniline is an aromatic compound which is dissolved on heating by the aromatics indiesel oil. Aniline point apparatus, thermometer, electric heating device, pipette etc. Add more information about buying, selling and doing business with aniline offers from suppliers providers of aniline 0 add. High aniline point indicates that the fuel is highly paraffinic and hence has a high diesel index and very good ignition quality. Then pour the hot liquid into 200 ml of cold water with constant stirring. Test method a is suitable for transparent samples with an initial boiling point above room temperature and where the aniline point is below the bubble point and above the solidification point of the aniline sample mixture. Aniline point article about aniline point by the free.
Standard test methods for aniline point and mixed aniline. The main effect of aniline by any route of exposure is a blood disorder in which oxygen delivery to the tissues is impaired. Pdf converter convert files to and from pdfs free online. More aromatics are typically present when there is a low aniline point. Utube aniline point apparatus, aldrich 3methylthioaniline, 97%, aniline, analytical standard, aniline point standard, astm. D611 aniline point standards spectrum quality standards. The aniline point determines the hydrocarbon composition of a particular oil. The higher the aniline point of the oil, the more desirable it is for drilling fluid usage. The tool will instantly upload and transform the file into a pdf. Method a is suitable for transparent samples with an initial boiling point above room temperature and where the aniline point is below the bubble point and above the solidification point of the anilinesample mixture. In technical oil, the aniline point is used to measure. This test is an important parameter used in characterization of pure hydrocarbons and hydrocarbon mixtures, including.
Product description thin film aniline point apparatus conforms to astm d611 and related specifications. This analysis is used more for technical white mineral oils, not for pharmaceutical grade. Its name is taken from the specific name of the indigoyielding plant indigofera anil indigofera suffruticosa. The aniline point is a physical characteristic of hydrocarbon compounds, such as oils, and refers to the minimum temperature at which the hydrocarbon and the same amount of the compound aniline c 5 h 5 nh 2 are perfectly miscible. The aap5 aniline point tester automates the aniline point test of petroleum products. At temperatures below this point, a mixture of the compound and an equal volume of aniline will not dissolve together. This condition is known as methemoglobinemia and its severity depends on how much. By definition, the aniline point is the lowest temperature at which equal volumes of aniline and oil are completely miscible clear. The aniline point of an oil is defined as the minimum temperature at which equal volumes of aniline c. Aniline damages hemoglobin, a protein that normally transports oxygen in the blood. Critical solution point for the oilaniline system as a measure of oil solubility article pdf available in fuel 8616. At the present time, the largest market for aniline is preparation of methylene diphenyl diisocyanate mdi, a key intermediate for polyurethanes. Properties of new siliconeacrylic rubber 1 aniline point degrees c 124 plus or minus 1. The minimum temperature at which a mixture of aniline, heptane, and hydrocarbon will form a solution.
The volume swell of qa was larger than that of acm1 and acm2 and also larger than the volume expected from the aniline point of the engine oil. Significant exposure may occur only if you work with aniline. Stirs anilinesample mixture in a borosilicate glass thin film tube suspended in a heating bath. The value gives an approximation for the content of aromatic compounds in the oil, since the miscibility of aniline, which is also an aromatic compound suggests the presence of similar i. It ignites readily, burning with a smoky flame characteristic of aromatic compounds. The instrument is based on the prc standard gb t 262. Aniline astm d611abcd ip 2abcd aniline point and mixed aniline point of petroleum products and hydrocarbon solvents method a is suitable for transparent samples with an initial boiling point above room temperature and where the aniline point is below the bubble point and above the. Koehler k10190 10191 manual aniline point apparatus astm. Most of petroleum products as well as rpo well known by their aniline point, especially those that are lighter, solvents used for other types of materials. Astm d611 122016 standard test methods for aniline point. Method a is suitable for transparent samples with an initial boiling point above room temperature and where the aniline point is below the bubble point and above the solidification point of the aniline sample mixture. Some more complicated molecules with other substituents can also be referred to as nitroanilines, for. Soda pdf creator online offers a full set of features directly in your web browser.
Other names and designations for aniline product synonym of aniline product translation for aniline other ways to refer to. The aniline index can be converted back into the aniline point by the following function. High aniline point the greater the aniline point, the lower the aromatics in diesel oil. It is mainly used as a raw material in the production of methylene diphenyl diisocyanate mdi, an intermediate in polyurethane manufacture. D college of engineering, organized by coanchor instituteldce. The unit is capable of covering a wide range of samples including transparent samples as well as darkopaque samples. It was first produced in 1826 and, currently, is one of the most produced nitrogen. Pdf aniline an is an important organic chemical commodity with an annual worldwide production at levels of mt. Aniline point for petroleum productes linkedin slideshare. D611 aniline point standards the accuracy of automated aniline point apparatus can be verified using a range of standards whose aniline points are determined using astm d611 method a. If aniline point is low then the aromatic content of the oil is more than the alkane paraffinic content and the vice versa.
Fit a reflux watercondenser to the flask and gently boil the mixture for 10 min. Sections i health hazard assessments for noncarcinogenic effects and. Aniline is a manufactured chemical used by a number of industries. Koehler k10190 10191 manual aniline point apparatus. The aniline point is a physical characteristic of hydrocarbon compounds, such as oils, and refers to the minimum temperature at which the hydrocarbon and the same amount of the compound aniline c5h5nh2 are perfectly miscible. Utube aniline point apparatus, aldrich 3methylthio aniline, 97%, aniline, analytical standard, aniline point standard, astm. Compress, edit or modify the output file, if necessary. Consisting of a phenyl group attached to an amino group, aniline is the simplest aromatic amine. What is the significance of the aniline point test. Mixed aniline point article about mixed aniline point by. Stirs aniline sample mixture in a borosilicate glass thin film tube suspended in a heating bath. For higharomatic products, such as aromatic extracts, the aniline point is around 20 c40 c. Apex largest professional lab equipment supplier in china. The aniline point ap correlates roughly with the amount and type of aromatic hydrocarbons in an oil sample.
Phenylamine, aminobenzene, benzenamine is a toxic organic compound, the simplest of the primary aromatic amines. A bottle top dispenser can be connected to the measuring cell for directly delivering aniline without a manual pipetting. Thin film of mixture flows over a light well illuminated by a variable 6v lamp. Apr 25, 2020 the aniline point is a physical characteristic of hydrocarbon compounds, such as oils, and refers to the minimum temperature at which the hydrocarbon and the same amount of the compound aniline c 5 h 5 nh 2 are perfectly miscible. It is an important starting material for making organic compounds such as drugs, explosives, and dyes. The aniline point is called the aniline point temperature, which is the lowest temperature f or c at which equal volumes of aniline c 6 h 5 nh 2 and the oil form a single phase.
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